Ryan Reynolds & Blake Lively

Ryan Reynold and Blake Lively completely caught the world off guard when they got married in 2012. They met while filming Green Lantern in 2010 while Reynolds was still married to Avengers star Scarlett Johansson. While Green Lantern was a bomb, their off-screen chemistry continued to flourish.

They started dating in 2011 after Reynolds and Johansson split up. Their wedding came under scrutiny after it was revealed that their venue has links to the slave trade. They were heavily criticized and profusely apologized for their mistake. They even renewed their vows in a private ceremony. Reynolds is the big earner in this family with a net worth of $100 million.